THE REACTION OF PHOSPHORUS TRICHLORIDE WITH PROPANOLAMINE-1.3

Authors
MUNDT C RIESEL L
Citation
C. Mundt et L. Riesel, THE REACTION OF PHOSPHORUS TRICHLORIDE WITH PROPANOLAMINE-1.3, Phosphorus, sulfur and silicon and the related elements, 88(1-4), 1994, pp. 179-183
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
88
Issue
1-4
Year of publication
1994
Pages
179 - 183
Database
ISI
SICI code
1042-6507(1994)88:1-4<179:TROPTW>2.0.ZU;2-X
Abstract
The reaction of PCl3 with propanolamine-1.3 in the presence of NEt(3) was studied and found to form two heterocyclic compounds, the loro-3-d ichlorophosphanyl-1.3.2-oxazaphosphorinane and the 2-aminopropoxy-1.3. 2-oxazaphosphorinane, which could be isolated and characterized. By lo w-temperature NMR the formation of the loro-3-dichlorophosphanyl-1.3.2 -oxazaphosphorinane was found to proceed via a diphosphanylated propan olamine-1.3.