SULFUR-MEDIATED (OR SELENIUM)-MEDIATED SYNTHESIS OF METHANOANTHRACENEDERIVATIVES - THE FIRST SYNTHESIS OF A SELENO-CYANOHYDRIN

Citation
N. Pelloux et al., SULFUR-MEDIATED (OR SELENIUM)-MEDIATED SYNTHESIS OF METHANOANTHRACENEDERIVATIVES - THE FIRST SYNTHESIS OF A SELENO-CYANOHYDRIN, Phosphorus, sulfur and silicon and the related elements, 89(1-4), 1994, pp. 17-23
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
10426507
Volume
89
Issue
1-4
Year of publication
1994
Pages
17 - 23
Database
ISI
SICI code
1042-6507(1994)89:1-4<17:S
Abstract
A synthesis of thio- and seleno-substituted 9,10-dihydro-9,10-methanoa nthracene derivatives is reported. They are obtained by Wittig rearran gement from 11-thia and 11-selena-9,10-dihydro-9,10-ethanoanthracene d erivatives. This rearrangement is applied to the first synthesis of a seleno-cyanohydrin (R(1)R(2)C(SeH)CN).