ON THE SCENT OF DANDELION DENDRIMERS .1. CYCLOPHOSPHAZENIC HEXAPODANES AS NEW CORES

Authors
SOURNIES F LABROUSSE L GRAFFEUIL M CRASNIER F FAUCHER JP LABARRE MC LABARRE JF
Citation
F. Sournies et al., ON THE SCENT OF DANDELION DENDRIMERS .1. CYCLOPHOSPHAZENIC HEXAPODANES AS NEW CORES, Phosphorus, sulfur and silicon and the related elements, 89(1-4), 1994, pp. 47-56
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
89
Issue
1-4
Year of publication
1994
Pages
47 - 56
Database
ISI
SICI code
1042-6507(1994)89:1-4<47:OTSODD>2.0.ZU;2-W
Abstract
Aminolysis of N3P3Cl3 by long-chain diamines, H2N-(CH2)(n)-NH2 (n grea ter than or equal to 6), leads regiospecifically to hexadangling (or h exapodanes) monomeric species provided it was achieved on alumina impr egnated with potassium hydroxide. These reactions run instantaneously at room temperature. Such hexapodanes constitute starting materials (c ores) for future design of spherical (i.e. aesthetically similar to dr y dandelion flowers) cyclophosphazenic dendrimers.