KINETIC-STUDIES ON THE REACTION OF SULFINIC ACIDS WITH CONJUGATED ALKENES .2. KINETICS OF THE ADDITION OF ARENESULFINIC ACIDS TO 4-SUBSTITUTED 2-NITROETHENYLARENES

Authors
ALEKSIEV DI IVANOVA S
Citation
Di. Aleksiev et S. Ivanova, KINETIC-STUDIES ON THE REACTION OF SULFINIC ACIDS WITH CONJUGATED ALKENES .2. KINETICS OF THE ADDITION OF ARENESULFINIC ACIDS TO 4-SUBSTITUTED 2-NITROETHENYLARENES, Phosphorus, sulfur and silicon and the related elements, 90(1-4), 1994, pp. 41-45
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
90
Issue
1-4
Year of publication
1994
Pages
41 - 45
Database
ISI
SICI code
1042-6507(1994)90:1-4<41:KOTROS>2.0.ZU;2-H
Abstract
The kinetics of the addition of arenesulfinic acids to 4-substituted 2 -nitroethenylarenes was studied by means of UV spectrophotometry. The effect of 4-substituting groups in benzenesulfinic acids, and the chan ge in reactivity of nitroethylene system due to typical electron-donat ing and electron-withdrawing groups were investigated. The substituent effect on benzenesulfinic acid fits Hammett's equation, p-value at 29 8 K being -1.12 (r = 0.987). Kinetic studies were carried out at 288-3 08 K, and the activating energy and the enthalpy of activation were de termined.