ON THE SCENT OF DANDELION DENDRIMERS .2. CYCLOPHOSPHAZENIC DECAPODANES AS NEW CORES

Authors
SOURNIES F FOUGA C GRAFFEUIL M FAUCHER JP CRASNIER F LABARRE MC LABARRE JF
Citation
F. Sournies et al., ON THE SCENT OF DANDELION DENDRIMERS .2. CYCLOPHOSPHAZENIC DECAPODANES AS NEW CORES, Phosphorus, sulfur and silicon and the related elements, 90(1-4), 1994, pp. 159-169
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
90
Issue
1-4
Year of publication
1994
Pages
159 - 169
Database
ISI
SICI code
1042-6507(1994)90:1-4<159:OTSODD>2.0.ZU;2-4
Abstract
Aminolysis of two-ring bridged-assembly cyclophosphazenes (coded as bi no moieties) by long-chain diamines, H2N-(CH2)(n)-NH2 (n greater than or equal to 6), leads regiospecifically to decadangling (or decapodane s or decapus) monomeric species provided it was achieved on alumina im pregnated with a suitable amount of potassium hydroxide. These reactio ns run very fast at room temperature. Such decapodanes constitute star ting materials (spherical bi-cores) for future design of cyclophosphaz enic dandelion dendrimers.