MASS-SPECTROMETRIC STUDY ON SOME O-(3-OXO -2-PHENYL 2H-PYRIDAZINE-6 YL) THIOPHOSPHOROORGANIC ESTERS

Citation
R. Popescu et al., MASS-SPECTROMETRIC STUDY ON SOME O-(3-OXO -2-PHENYL 2H-PYRIDAZINE-6 YL) THIOPHOSPHOROORGANIC ESTERS, Phosphorus, sulfur and silicon and the related elements, 91(1-4), 1994, pp. 9-19
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
10426507
Volume
91
Issue
1-4
Year of publication
1994
Pages
9 - 19
Database
ISI
SICI code
1042-6507(1994)91:1-4<9:MSOSO->2.0.ZU;2-A
Abstract
The interpretation of the electron impact mass spectra of O-(3-oxo 2-p henyl 2H-pyridazine-6 yl) diethylphosphinothioate (I), O-(3-oxo 2-phen yl 2H-pyridazine-6 yl) dipropylphosphinothioate (II), O-(3-oxo 2-pheny l 2H-pyridazine-6 yl) diphenylphosphionothioate (III), O-(3-oxo 2-phen yl 2H-pyridazine-6 yl) O,O-diphenyl phosphorothioate (IV), and 2-O-(3- oxo 2-phenyl 2H-pyridazine-6 yl) 2-thiono 5,5-dimetyl 1,3,2-dioxaphosp horinan (V) is presented. Elucidation of the fragmentation pathways wa s aided by metastable transitions of all the compounds and by exact ma ss measurements on compounds (II) and (V).