SYNTHESIS AND TETRAKIS(TRIMETHYLSILYLMETH YL)DISTIBANE AND REACTIONS OF DITELLURIDES OR TELLURIUM

Authors
BREUNIG HJ KALLER R SILVESTRU A
Citation
Hj. Breunig et al., SYNTHESIS AND TETRAKIS(TRIMETHYLSILYLMETH YL)DISTIBANE AND REACTIONS OF DITELLURIDES OR TELLURIUM, Phosphorus, sulfur and silicon and the related elements, 91(1-4), 1994, pp. 165-168
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
91
Issue
1-4
Year of publication
1994
Pages
165 - 168
Database
ISI
SICI code
1042-6507(1994)91:1-4<165:SATYAR>2.0.ZU;2-O
Abstract
Elimination of Me(3)SiCH(2)Br from (Me(3)SiCH(2))(3)SbBr2 leads to (Me (3)SiCH(2))(2)SbBr (1). Reaction of 1 with Mg in tetrahydrofuran gives [(Me(3)SiCH(2))(2)Sb](2) (2). Complete exchange reactions of 2 with R TeTeR afford (Me(3)SiCH(2))(2) SbTeR (3: R = Ph, 4: R = p-Tol). [(Me(3 )SiCH(2))(2)Sb]Te-2 (5) is formed by insertion of Te into 2 or better by the reaction of 1 with Na2Te.