GENERATION OF SILICON MONOXIDE, SILICON MONOSULFIDE AND HYDROGEN SILAISOCYANIDE BY FLASH VACUUM THERMOLYSIS

Authors
CHIVE A LEFEVRE V SYSTERMANS A RIPOLL JL BOGEY M WALTERS A
Citation
A. Chive et al., GENERATION OF SILICON MONOXIDE, SILICON MONOSULFIDE AND HYDROGEN SILAISOCYANIDE BY FLASH VACUUM THERMOLYSIS, Phosphorus, sulfur and silicon and the related elements, 91(1-4), 1994, pp. 281-284
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
91
Issue
1-4
Year of publication
1994
Pages
281 - 284
Database
ISI
SICI code
1042-6507(1994)91:1-4<281:GOSMSM>2.0.ZU;2-P
Abstract
The flash vacuum thermolysis (650-1000 degrees C) of unsaturated di-t- butylsilyl ether, sulfide, and amine 7-9 gave, upon retro-ene reaction , beta-elimination of isobutene and dehydrogenation, silicon monoxide (4), silicon monosulfide (5), and hydrogen silaisocyanide (6), charact erized in the gas-phase by millimeter wave spectrometry.