A FACILE SYNTHESIS OF NEW UNSYMMETRICAL AZINES BY CYCLODESULFURIZATION REACTIONS OF DITHIOESTERS WITH DIAMINES

Authors
HASSAN SM
Citation
Sm. Hassan, A FACILE SYNTHESIS OF NEW UNSYMMETRICAL AZINES BY CYCLODESULFURIZATION REACTIONS OF DITHIOESTERS WITH DIAMINES, Phosphorus, sulfur and silicon and the related elements, 92(1-4), 1994, pp. 213-217
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
92
Issue
1-4
Year of publication
1994
Pages
213 - 217
Database
ISI
SICI code
1042-6507(1994)92:1-4<213:AFSONU>2.0.ZU;2-E
Abstract
Dithioesters 2a, b were prepared and methylated to give dimethyl thioe sters 3a, b. Azines 4a-d and 5a, b were obtained in one step from 2 wi th primary diamines or in two steps through 3. Dithioesters 2a, b reac ted with amines in ethanol to produce thiosemicarbazones 6a, b and 8a- d, while in butanol reacted with morpholine to form 7a, b.