R. Streubel et A. Kusenberg, SYNTHESIS, STRUCTURE AND REACTIONS OF 2H-1-AZA-2-PHOSPHIRENE DERIVATIVES, Phosphorus, sulfur and silicon and the related elements, 93(1-4), 1994, pp. 281-284
Reactions of amino(aryl)carbenepentacarbonylmetal complexes with chlor
ophosphane derivatives under basic conditions yield 2H-1-aza-2-phosphi
rene metal complex derivatives. First investigations of thermally indu
ced ring-opening reaction of a 2H-1-aza-2-phosphirene tungsten derivat
ive in the presence of various trapping reagents are presented.