FLUORIDE-ION ATTACK TOWARDS TRIAZINES

Authors
LORK E CHEN SJ KNITTER G MEWS R
Citation
E. Lork et al., FLUORIDE-ION ATTACK TOWARDS TRIAZINES, Phosphorus, sulfur and silicon and the related elements, 93(1-4), 1994, pp. 309-311
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
93
Issue
1-4
Year of publication
1994
Pages
309 - 311
Database
ISI
SICI code
1042-6507(1994)93:1-4<309:FATT>2.0.ZU;2-5
Abstract
From the reaction of TAS-fluoride (Me(2)N)(3)S(+)Me(3)SiF(2)(-)(1) and fluorotriazines (FCN)(n)(FSN)(3-n) (n = 1-3) and sulfanuric fluoride (FS(O)N)(3) stable salts with the anions [(F2CN)(FCN)(n-1)(FSN)(3-n)]( -) and [(NS(O)F)(3)F](-) are isolated. Interaction with P3N3F6 gives ( TAS(+))(2) P3N3F5NPF2NPF2NPF52-, a cyclic-acyclic dianion. From the ad dition of F- to CF2- CF2-N = S = N cyclic bis(imino)fluorosulfinate is formed, from S4N4 and 1 TAS(+) S3N3- is obtained.