A MULTINUCLEAR NMR-STUDY OF THE CYCLOADDITION REACTION OF SNSASF(6)WITH THE PHOSPHAALKYNE (CH3)(3)CCP - REDUCTION OF THE 6-PI CYCLOADDUCT 1,3,2,4-DITHIAZOPHOSPHOLIUM (CH3)(3)CCPSNS+

Authors
PARSONS S PASSMORE J SUN XP
Citation
S. Parsons et al., A MULTINUCLEAR NMR-STUDY OF THE CYCLOADDITION REACTION OF SNSASF(6)WITH THE PHOSPHAALKYNE (CH3)(3)CCP - REDUCTION OF THE 6-PI CYCLOADDUCT 1,3,2,4-DITHIAZOPHOSPHOLIUM (CH3)(3)CCPSNS+, Phosphorus, sulfur and silicon and the related elements, 93(1-4), 1994, pp. 435-436
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
93
Issue
1-4
Year of publication
1994
Pages
435 - 436
Database
ISI
SICI code
1042-6507(1994)93:1-4<435:AMNOTC>2.0.ZU;2-Z
Abstract
The cycloaddition reaction of SNS+ (as the AsF6- salt) with the phosph aalkyne (CH3)(3)CCP gave (CH3)(3)CCPSNS+ the first example of any 1,3, 2,4-dithiazophospholium heterocycle. Reduction of 6 pi (CH3)(3)CCPSNS in situ with SbPh(3) in the presence of Me(4)NCl probably led to a ne w 7 pi 1,3,2,4-dithiazophospholyl (CH3)(3)CCPSNS radical.