PREPARATION, STRUCTURE AND CHEMISTRY OF A NOVEL, DISJOINT DIRADICAL, 4,4'-BIS(1,2,3,5-DITHIADIAZOLYL)

Authors
HICKS RG MACKINNON CD OAKLEY RT BRYAN CD CORDES AW HADDON RC
Citation
Rg. Hicks et al., PREPARATION, STRUCTURE AND CHEMISTRY OF A NOVEL, DISJOINT DIRADICAL, 4,4'-BIS(1,2,3,5-DITHIADIAZOLYL), Phosphorus, sulfur and silicon and the related elements, 93(1-4), 1994, pp. 439-440
Citations number
3
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
93
Issue
1-4
Year of publication
1994
Pages
439 - 440
Database
ISI
SICI code
1042-6507(1994)93:1-4<439:PSACOA>2.0.ZU;2-L
Abstract
The reaction of oxamidrazone with SCl2 affords 4,4'-bis(1,2,3,5-dithia diazolium) dichloride, which can be reduced to the corresponding bis(1 ,2,3,5-dithiadiazolyl) diradical; the electronic structure of the dira dical is discussed, and the solid state structure, charge transfer che mistry and transport properties of the dimer [S2N2CCN2S2](2) are descr ibed.