PREPARATION AND STRUCTURE OF A 16-MEMBERED RING WITH ALTERNATING CN AND SN GROUPS

Authors
ZORICAK P PARVEZ M VARGASBACA I CHIVERS T
Citation
P. Zoricak et al., PREPARATION AND STRUCTURE OF A 16-MEMBERED RING WITH ALTERNATING CN AND SN GROUPS, Phosphorus, sulfur and silicon and the related elements, 93(1-4), 1994, pp. 455-456
Citations number
2
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
93
Issue
1-4
Year of publication
1994
Pages
455 - 456
Database
ISI
SICI code
1042-6507(1994)93:1-4<455:PASOA1>2.0.ZU;2-N
Abstract
The reaction of trisilylated benzamidines ArCN2(SiMe(3))(3) with PhSCl in a 1:3 molar ratio produces cyclic compounds of the type (ArCNS(Ph) N)(n) (n=2, 4) in addition the diazenes trans-PhSNC(Ar)N=NC(Ar)NSPh. T he X-ray structure of the sixteen-membered ring (4-BrC6H4)(4)C(4)N(8)S (4)Ph(4) has been determined.