UNEXPECTED SUBSTITUTION-REACTIONS OF 1,3-DITHIETANE-1,1,3,3-TETRAOXIDE (DISULPHENE)

Authors
SUNDERMEYER W WALCH A
Citation
W. Sundermeyer et A. Walch, UNEXPECTED SUBSTITUTION-REACTIONS OF 1,3-DITHIETANE-1,1,3,3-TETRAOXIDE (DISULPHENE), Phosphorus, sulfur and silicon and the related elements, 93(1-4), 1994, pp. 477-478
Citations number
3
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
93
Issue
1-4
Year of publication
1994
Pages
477 - 478
Database
ISI
SICI code
1042-6507(1994)93:1-4<477:USO1>2.0.ZU;2-5
Abstract
1,3-Dithietane-1,1,3,3-tetraoxide (''disulphene'') is a versatile reag ent for the synthesis of sulphenes and sulphines(1). Upon investigatin g silylation reactions of disulphene (1) an unexpected O-silylation yi elding a sulphoxoniumylide was found(2). The synthesis of more stable sulphoxoniumylides will be reported(3).