FREE-RADICAL AND ELECTROCHEMICALLY INDUCED OXIDATION OF ORGANIC SULFUR-COMPOUNDS, SELENIUM-COMPOUNDS AND PHOSPHORUS-COMPOUNDS

Authors
TOBIEN T HUNGERBUHLER H ASMUS KD
Citation
T. Tobien et al., FREE-RADICAL AND ELECTROCHEMICALLY INDUCED OXIDATION OF ORGANIC SULFUR-COMPOUNDS, SELENIUM-COMPOUNDS AND PHOSPHORUS-COMPOUNDS, Phosphorus, sulfur and silicon and the related elements, 95-6(1-4), 1994, pp. 249-263
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
95-6
Issue
1-4
Year of publication
1994
Pages
249 - 263
Database
ISI
SICI code
1042-6507(1994)95-6:1-4<249:FAEIOO>2.0.ZU;2-F
Abstract
A series of MeS(CH2)(n)SMe, MeS(CH2)(n)SeMe, MeSe(CH2)(n)SeMe (with n = 1-5), and RS(CH2)(n)PEt(2) (n = 2-4) have been investigated with res pect to their radiation chemical one-electron and electrochemical two- electron oxidations. The results essentially confirm an interaction of the two respective heteroatoms in these compounds already in the unox idized state. Oxidation is thus achieved by removal of antibonding sig ma electrons.