PREPARATION AND REACTIONS OF SUBSTITUTED ETHENESULFENATE ANIONS

Authors
SCHWAN AL REFVIK MD
Citation
Al. Schwan et Md. Refvik, PREPARATION AND REACTIONS OF SUBSTITUTED ETHENESULFENATE ANIONS, Phosphorus, sulfur and silicon and the related elements, 95-6(1-4), 1994, pp. 327-328
Citations number
3
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
95-6
Issue
1-4
Year of publication
1994
Pages
327 - 328
Database
ISI
SICI code
1042-6507(1994)95-6:1-4<327:PAROSE>2.0.ZU;2-7
Abstract
Trans-alkyl and gem-silyl substituted ethenesulfenate anions result fr om the reaction of hexamethyldisilazide bases with anti-alkyl and anti -silyl substituted thiirane-S-oxides, respectively, via a stereoselect ive deprotonation process. The sulfenates can be captured at sulfur wi th certain alkyl halides or they can be converted to a series of subst ituted ethenesulfenic acid amides.