METALATED 2-ALKENYLSULFOXIMINES - REACTIVITY AND NMR-SPECTROSCOPIC STUDIES

Authors
REGGELIN M WEINBERGER H
Citation
M. Reggelin et H. Weinberger, METALATED 2-ALKENYLSULFOXIMINES - REACTIVITY AND NMR-SPECTROSCOPIC STUDIES, Phosphorus, sulfur and silicon and the related elements, 95-6(1-4), 1994, pp. 341-342
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
95-6
Issue
1-4
Year of publication
1994
Pages
341 - 342
Database
ISI
SICI code
1042-6507(1994)95-6:1-4<341:M2-RAN>2.0.ZU;2-7
Abstract
Enantiomerically pure, metalated 2-Alkenylsulfoximines were used to pr epare gamma-hydroxyvinylsulfoximines yielding very high diastereomeric excesses. Experiments with epimeric mixtures and NMR-spectroscopic st udies of the lithiated intermediates demonstrate their configurational lability as opposed to the assumed configurational stability of the t itanium compound.