STEREOCHEMISTRY OF PROTIODESILYLATION OF 3-TRIMETHYLSILYL-2-THIABICYCLO[2.2.1]HEPTENES, HEPTANES AND DERIVATIVES

Authors
BONINI BF MASI E MASIERO S MAZZANTI G ZANI P
Citation
Bf. Bonini et al., STEREOCHEMISTRY OF PROTIODESILYLATION OF 3-TRIMETHYLSILYL-2-THIABICYCLO[2.2.1]HEPTENES, HEPTANES AND DERIVATIVES, Phosphorus, sulfur and silicon and the related elements, 95-6(1-4), 1994, pp. 379-380
Citations number
1
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
95-6
Issue
1-4
Year of publication
1994
Pages
379 - 380
Database
ISI
SICI code
1042-6507(1994)95-6:1-4<379:SOPO3>2.0.ZU;2-A
Abstract
Some 3-trimethylsilyl-2-thiabicyclo[2.2.1]heptenes and heptanes of kno wn configuration were protiodesilylated and the stereochemistry of the reaction was studied. Evidences for a carbanionic intermediate as wel l as the pivotal role played by the metal counter-ion are described.