FORMATION OF A NEW ACTIVE OXIDIZING SPECIES IN PHOTOSENSITIZED OXYGENATION OF HETEROATOM COMPOUNDS

Authors
AKASAKA T ANDO W
Citation
T. Akasaka et W. Ando, FORMATION OF A NEW ACTIVE OXIDIZING SPECIES IN PHOTOSENSITIZED OXYGENATION OF HETEROATOM COMPOUNDS, Phosphorus, sulfur and silicon and the related elements, 95-6(1-4), 1994, pp. 437-438
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
95-6
Issue
1-4
Year of publication
1994
Pages
437 - 438
Database
ISI
SICI code
1042-6507(1994)95-6:1-4<437:FOANAO>2.0.ZU;2-G
Abstract
Singlet oxygen oxidation of heteroatom compounds caused cooxidation of olefin epoxides. A persulfoxide intermediate generated in singlet oxy gen oxidation of sulfide can transfer an oxygen atom to iron(lll) porp hyrin to form the iron oxo species. A phosphadioxirane is proposed as the labile intermediate formed in singlet oxygen oxidation of phosphit e. These active oxidizing species are responsible for epoxidation of o lefins.