INTRAMOLECULAR DIELS-ALDER REACTIONS OF VINYLSULFONATES

Authors
CRAMER E FLEISCHER M MEINERS U STOLTING J METZ P
Citation
E. Cramer et al., INTRAMOLECULAR DIELS-ALDER REACTIONS OF VINYLSULFONATES, Phosphorus, sulfur and silicon and the related elements, 95-6(1-4), 1994, pp. 487-488
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
95-6
Issue
1-4
Year of publication
1994
Pages
487 - 488
Database
ISI
SICI code
1042-6507(1994)95-6:1-4<487:IDROV>2.0.ZU;2-0
Abstract
Control of side chain chirality is efficiently achieved by intramolecu lar Diels-Alder cycloaddition of vinylsulfonates and subsequent oxidat ive or reductive desulfurization of the resultant sultones. An alkoxid e directed regio- and stereoselective 1,6-addition to dienyl sultones further enhances the utility of this reaction sequence.