It was noticed 60 years ago that at sunrise (i) the ionospheric critic
al frequency foF2 increases faster in winter than in summer and (ii) t
he increase begins at a greater solar zenith angle in winter. It was l
ater suggested that this ''seasonal sunrise anomaly'' is due to a seas
onal change of atomic/molecular ratio in the neutral air in the F2-lay
er. This paper uses the Sheffield University plasmaphere-ionosphere co
mputational model (SUPIM) with the MSIS thermosphere model to examine
the relative importance at sunrise of production, loss and diffusion p
rocesses, and the effect of neutral air winds. The results show that b
oth (i) and (ii) can be explained in terms of neutral composition chan
ges.