Ultradeep, or ultra-high-pressure (UHP), metamorphic rocks, formed fro
m crustal protoliths within the stability field of coesite at pressure
s >2.5-3.0 GPa corresponding to depths >80-120 km, occur locally thoug
h regionally distributed in at least five continental areas. Their rec
ognition is solely based on characteristic minerals and mineral assemb
lages calibrated by experimental high-pressure studies, Detailed petro
graphic and microprobe work, especially on mineral inclusions, in favo
rable cases allows the derivation of prograde PT paths during subducti
on and of retrograde ones during exhumation. Commonly, the gneisses ad
jacent to the UHP rocks do not exhibit signs of ultradeep metamorphism
, apparently because the kinetics of their mineral reactions are suffi
ciently fast to allow complete reequilibration to shallower PT conditi
ons during the retrograde path. It is also possible, however, that UHP
equilibria were not attained throughout the rock volumes subducted, b
ut only along zones of shearing and fluid introduction. If it is true
that not all UHP metamorphic rocks return to the crustal orogenic belt
s, but some continue to be subducted to greater mantle depths, the cla
ssical geochemical pattern of a one-way mass transfer from mantle to c
rust throughout the Earth's history is at stake. The assumed gradual g
rowth of continents may have had a counterpart of continent destructio
n during collision events. Most recent experimental studies at high pr
essures and relatively low temperatures show that at least three new h
ydrous (Mg)Al-silicates exist that were not found in nature thus far,
but may be characteristic minerals in the cold portions of old subduct
ion zones, thus extending the water retentivity of subducting slabs to
greater, and hitherto unexpected, depths.