THE BEHAVIOR OF THE FURAZAN-N-METHANIDE ANALOG OF THE FUROXAN SYSTEM - RING EXPANSION - NEW ROUTES TO 6H-1,2,5-OXADIAZINES - A COMBINED EXPERIMENTAL AND THEORETICAL-STUDY

Citation
Rn. Butler et al., THE BEHAVIOR OF THE FURAZAN-N-METHANIDE ANALOG OF THE FUROXAN SYSTEM - RING EXPANSION - NEW ROUTES TO 6H-1,2,5-OXADIAZINES - A COMBINED EXPERIMENTAL AND THEORETICAL-STUDY, Journal of the Chemical Society. Perkin transactions. I, (9), 1995, pp. 1083-1084
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
0300922X
Issue
9
Year of publication
1995
Pages
1083 - 1084
Database
ISI
SICI code
0300-922X(1995):9<1083:TBOTFA>2.0.ZU;2-W
Abstract
Desilylation of N-trimethylsilylmethyl- and deprotonation of N-methyl- 1,2,5-oxadiazolium (furazan) salts gave ring expansions to 6H-1,2,5-ox adiazines; the results of 6-31G calculations on the expected furazan-N -methanide intermediate are reported.