MOLECULAR JUMPS WITHIN THE FAST MOTION LIMIT - THE INFLUENCE OF UNEQUALLY POPULATED SITES ON H-2-SOLID STATE NMR LINESHAPES

Authors
REICHERT D SCHNEIDER H
Citation
D. Reichert et H. Schneider, MOLECULAR JUMPS WITHIN THE FAST MOTION LIMIT - THE INFLUENCE OF UNEQUALLY POPULATED SITES ON H-2-SOLID STATE NMR LINESHAPES, Zeitschrift für physikalische Chemie, 190, 1995, pp. 63-71
Citations number
8
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Journal title
Zeitschrift für physikalische Chemie → ACNP
ISSN journal
09429352
Volume
190
Year of publication
1995
Part
1
Pages
63 - 71
Database
ISI
SICI code
0942-9352(1995)190:<63:MJWTFM>2.0.ZU;2-B
Abstract
Motional narrowed H-2-solid state lineshapes of a jumping C-D-bond are strongly influenced by unequally populated sites accessible by the bo nd. It is possible to calculate parameters that describe the Lineshape s in the fast motion region using basic mathematics. These parameters can be calculated analytically from the parameters describing molecula r geometry.