2ND-CHANNEL DESIGNS FOR A SINGLE-CHANNEL FLAME PHOTOMETRIC DETECTOR

Citation
Wa. Aue et al., 2ND-CHANNEL DESIGNS FOR A SINGLE-CHANNEL FLAME PHOTOMETRIC DETECTOR, Journal of chromatography, 699(1-2), 1995, pp. 195-201
Citations number
17
Categorie Soggetti
Chemistry Analytical
Journal title
Volume
699
Issue
1-2
Year of publication
1995
Pages
195 - 201
Database
ISI
SICI code
Abstract
An existing, one-channel flame photometric detector was modified so th at it would operate with higher sensitivity on two channels. To do thi s, the available primary channel was first changed to holophotal mode by installing a parabolic mirror. Optical access to the flame was then secured for a secondary channel by drilling a coaxial hole through th e parabola. Two alternative designs were used for the secondary channe l: a light guide and a lens-mirror combination. They were tested with compounds of osmium, lead, sulfur and phosphorus. Both the new primary and either one of the two secondary channels yielded higher light thr oughput and lower detection limits than the initial, conventional chan nel.