2ND-ROW AND 3RD-ROW TRANSITION-METAL COMPLEXES OF DIHYDROXYBENZOIC ACIDS, AND THE CRYSTAL-STRUCTURE OF NTER-DOT-1.5H(2)O(2,3-H(2)DHB=2,3-DIHYDROXYBENZOIC ACID)

Authors
GRIFFITH WP NOGUEIRA HIS PARKIN BC SHEPPARD RN WHITE AJP WILLIAMS DJ
Citation
Wp. Griffith et al., 2ND-ROW AND 3RD-ROW TRANSITION-METAL COMPLEXES OF DIHYDROXYBENZOIC ACIDS, AND THE CRYSTAL-STRUCTURE OF NTER-DOT-1.5H(2)O(2,3-H(2)DHB=2,3-DIHYDROXYBENZOIC ACID), Journal of the Chemical Society. Dalton transactions, (11), 1995, pp. 1775-1781
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
11
Year of publication
1995
Pages
1775 - 1781
Database
ISI
SICI code
0300-9246(1995):11<1775:2A3TCO>2.0.ZU;2-5
Abstract
The new complexes [MO(2)L(2)](2-) (H(2)L = 2,3- or 3,4-dihydroxybenzoi c acid. 2,3-H(2)dhb or 3,4-H(2)dhb, M = Mo, W or Os; H(2)L = 2.6-dihyd roxybenzoic acid, 2,6-H(2)dhb, M = Mo), [OsO2(py)(2)(2,6-dhb)] (Py = P yridine), [ReO\(PPh(3))(2)L] (H(2)L = 2,3-, 3,4- or 2,6-H(2)dhb) and [ M(PPh(3))(2)(2,3-dhb)] (M = Pd or Pt) have been prepared. The crystal structure of [NMe(4)](2)[MoO2(2,3-dhb)(2)]. 1.5H(2)O has been determin ed and exhibits catecholato rather than salicylato type bonding. Infra red. Raman,H-1 and C-13- (H-1) NM R spectroscopic data for the complex es are also presented.