HETEROPOLYPEROXO-TUNGSTATES AND HETEROPOLYPEROXO-MOLYBDATES AND ISOPOLYPEROXO-TUNGSTATES AND ISOPOLYPEROXO-MOLYBDATES AS CATALYSTS FOR THE OXIDATION OF TERTIARY-AMINES, ALKENES AND ALCOHOLS

Authors
BAILEY AJ GRIFFITH WP PARKIN BC
Citation
Aj. Bailey et al., HETEROPOLYPEROXO-TUNGSTATES AND HETEROPOLYPEROXO-MOLYBDATES AND ISOPOLYPEROXO-TUNGSTATES AND ISOPOLYPEROXO-MOLYBDATES AS CATALYSTS FOR THE OXIDATION OF TERTIARY-AMINES, ALKENES AND ALCOHOLS, Journal of the Chemical Society. Dalton transactions, (11), 1995, pp. 1833-1837
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
11
Year of publication
1995
Pages
1833 - 1837
Database
ISI
SICI code
0300-9246(1995):11<1833:HAHAI>2.0.ZU;2-L
Abstract
The catalytic oxidation of tertiary amines to the corresponding N-oxid es by [XO(4){MO(O-2)(2)}(4)](3-) (X = P or As, M = Mo or W) and by [M( 2)O(3)(O-2)(4)](2-) with H2O2 as co-oxidant has been studied. Epoxidat ion of alkenes and oxidation of alcohols by [M(2)O(3)(O-2)(4)](2-) wit h H2O2 as co oxidant has also been examined and compared with that eff ected by [XO(4){MO(O-2)(2)}(4)](3-). A possible structure for [M(2)O(3 )(O-2)(4)](2-) is suggested.