UNUSUAL REACTIVITY OF POLY(TRIFLUOROMETHYL)BENZENES - SEMIEMPIRICAL REACTION MODELING

Authors
KORONIAK H FIEDOROW P DMOWSKI W PORWISIAK J
Citation
H. Koroniak et al., UNUSUAL REACTIVITY OF POLY(TRIFLUOROMETHYL)BENZENES - SEMIEMPIRICAL REACTION MODELING, Journal of molecular structure, 351, 1995, pp. 187-195
Citations number
7
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
351
Year of publication
1995
Pages
187 - 195
Database
ISI
SICI code
0022-2860(1995)351:<187:UROP-S>2.0.ZU;2-#
Abstract
The reaction of methyllithium with 1,3,5-tris(trifluoromethyl)benzene, 1, 1,2,4,5-tetrakis(trifluoromethyl)benzene, 2, and 1,2,4-tris(triflu oromethyl)benzene, 3, was analyzed using the semiempirical package MOP AC 6. It was shown that formation of lithium-hydrogen exchange product s are favoured only in the case of compound 1, whereas in the case of 2 and 3 the major products were those of nucleophilic substitution.