Thermal radiation absorption in metallic particles is an important phe
nomenon in many contemporary laser-processing techniques, including la
ser cladding of coating materials and laser cleaning of particulate co
ntaminations. In this work, the Drude free-electron theory and electro
magnetic wave theory are utilized to characterize the internal absorpt
ion of CO2 laser radiation in aluminum, chromium, and nickel particles
. The results show that metallic particles have unique radiation prope
rties. Radiation absorption in large particles occurs only in a very n
arrow region of the front particle surface, which results in inefficie
nt radiation absorption. On the other hand, micron and submicron parti
cles can absorb radiation very efficiently, due to the strong diffract
ion effect at the particle surface. For extremely small particles (e.g
., nanometer particles), radiation absorption becomes less efficient.
The particle absorption efficiency is found to increase with temperatu
re, and this temperature dependence can be determined from those of fl
at metal surfaces at the normal incidence.