THE MOLECULAR-STRUCTURE OF TETRAMETHYLOXORHENIUM, (CH3)(4)REO, BY GASELECTRON-DIFFRACTION

Authors
HAALAND A VERNE HP VOLDEN HV HERRMANN WA KIPROF P
Citation
A. Haaland et al., THE MOLECULAR-STRUCTURE OF TETRAMETHYLOXORHENIUM, (CH3)(4)REO, BY GASELECTRON-DIFFRACTION, Journal of molecular structure, 352, 1995, pp. 153-156
Citations number
13
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
352
Year of publication
1995
Pages
153 - 156
Database
ISI
SICI code
0022-2860(1995)352:<153:TMOT(B>2.0.ZU;2-R
Abstract
The gas electron diffraction data of tetramethyloxorhenium, (CH3)(4)Re O, recorded with a nozzle temperature of about 30 degrees C are consis tent with the molecular symmetry C-4v. Least-square refinements yield the bond distances (r(a)) Re=O = 168.2(3) pm and Re-C = 211.7(3) pm an d the valence angles angle C-Re-C = 82(1)degrees and angle C-Re-O = 11 2(1)degrees.