FACILE SYNTHESIS OF SN4N4 CUBANES - SYNTHESES AND STRUCTURES OF [SN(NC6H11)](4) AND [SN(2-NCH2C5H4N)](4)

Authors
ALLAN RE BESWICK MA EDWARDS AJ PAVER MA RENNIE MA RAITHBY PR WRIGHT DS
Citation
Re. Allan et al., FACILE SYNTHESIS OF SN4N4 CUBANES - SYNTHESES AND STRUCTURES OF [SN(NC6H11)](4) AND [SN(2-NCH2C5H4N)](4), Journal of the Chemical Society. Dalton transactions, (12), 1995, pp. 1991-1994
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
12
Year of publication
1995
Pages
1991 - 1994
Database
ISI
SICI code
0300-9246(1995):12<1991:FSOSC->2.0.ZU;2-P
Abstract
The low-temperature reaction of Sn(NMe(2))(2) with primary amines (NH( 2)R) (1:1 equivalents) is a general route by which imido tin(II) cuban es [Sn(NR)](4) can be prepared. It has been exemplified by the direct reactions of the relatively non-acidic primary amines NH2(C6H11) and 2 -H2NCH2C5H4N, producing the cubanes [Sn(NC6H11)](4) 1 and [Sn(2-NCH2C5 H4N)](4) 2. The structures of both complexes have been established by X-ray crystallography.