PREDICTION OF GAS-CHROMATOGRAPHIC RETENTION TIMES, COLUMN EFFICIENCY AND RESOLUTION AS A FUNCTION OF TEMPERATURE AND FLOW-RATE - APPLICATION FOR GAS-CHROMATOGRAPHIC SEPARATION OF 8 P-HYDROXYBENZOIC ESTERS

Citation
Y. Guillaume et al., PREDICTION OF GAS-CHROMATOGRAPHIC RETENTION TIMES, COLUMN EFFICIENCY AND RESOLUTION AS A FUNCTION OF TEMPERATURE AND FLOW-RATE - APPLICATION FOR GAS-CHROMATOGRAPHIC SEPARATION OF 8 P-HYDROXYBENZOIC ESTERS, Journal of chromatography, 704(2), 1995, pp. 437-447
Citations number
41
Categorie Soggetti
Chemistry Analytical
Journal title
Volume
704
Issue
2
Year of publication
1995
Pages
437 - 447
Database
ISI
SICI code
Abstract
Using eight p-hydroxybenzoic esters, simple equations were developed t o provide accurate gas chromatographic retention data and column effic iency represented by the height equivalent to a theoretical plate. Wit h an experimental design, these equations have practical applications in the calculation of the resolution for a given pair of these compoun ds and for the determination of the isothermal conditions for their se paration in minimum time. The method reduced the number of experiments to be carried out and provided good agreement between experimental re sults and predicted data.