J. Giacometti et al., MONITORING THE ESTERIFICATION OF SORBITOL AND FATTY-ACIDS BY GAS-CHROMATOGRAPHY, Journal of chromatography, 704(2), 1995, pp. 535-539
Lauric acid esters of sorbitol, 1,4-sorbitan and 1,4:3,6-isosorbide we
re synthesized in laboratory. Esterification was carried out at 160 de
grees C with a catalyst for sorbitol cyclization and esterification, v
iz., p-toluenesulfonic acid. Lipid classes and polyols were separated
and analysed by GC as trimethylsilyl ethers and esters. The purpose of
the study was to determine the suitability of GC analysis of these pr
oducts as a means of following the progress of reactions. The results
confirmed the possibility of monitoring lauric acid and sorbitol ester
ification via the GC determination of lauric acid concentration.