Y. Hayashi et al., AMMONIUM-SALT-ADDED SILICA SLURRY FOR THE CHEMICAL-MECHANICAL POLISHING OF THE INTERLAYER DIELECTRIC FILM PLANARIZATION IN ULSIS, JPN J A P 1, 34(2B), 1995, pp. 1037-1042
Based on the theory of colloid, a new KOH-free silica slurry is develo
ped for chemical mechanical polishing (CMP) to planarize the interlaye
r dielectric films in ULSI's. The ammonium salt addition to the slurri
es of pH = 6-7 promotes the silica particle agglomeration in the slurr
y, and enlarges the effective abrasive particle size. The particle agg
lomeration yields a high polishing rate due to increasing of the mecha
nical effect, and good particle removability with scrub cleaning is ac
hieved. The ammonium salt-added slurry provides the high-speed CMP wit
hout alkaline-metal contamination to the LSI fabrication line.