Ultra fine oxidized titanium (Ti) lines 18 nm wide and 3 nm high have
been formed on the surface of a 4 nm Ti layer on a SiO2/Si substrate u
sing the scanning tunneling microscope [STM] tip as-a selective anodiz
ation electrode. The dependence of the size of the oxidized titanium l
ine on the various parameters is investigated. The formed oxidized tit
anium line has resistivity of 2 x 10(4) ohm cm, which is a value seven
orders of magnitude higher than that of the deposited Ti layer. The o
xidized Ti line is used in the planar type metal-insulator-metal [MIM]
diode, and works as an energy barrier for the electron. The energy ba
rrier height of the oxidized Ti line is found to be delta E(g) = 0.25
eV.