3',4-DI-O-METHYLCEDRUSIN - SYNTHESIS, RESOLUTION AND ABSOLUTE-CONFIGURATION

Authors
LEMIERE G GAO M DEGROOT A DOMMISSE R LEPOIVRE J PIETERS L BUSS V
Citation
G. Lemiere et al., 3',4-DI-O-METHYLCEDRUSIN - SYNTHESIS, RESOLUTION AND ABSOLUTE-CONFIGURATION, Journal of the Chemical Society. Perkin transactions. I, (13), 1995, pp. 1775-1779
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
13
Year of publication
1995
Pages
1775 - 1779
Database
ISI
SICI code
0300-922X(1995):13<1775:3-SRAA>2.0.ZU;2-Z
Abstract
The title compound has been synthesised in racemic form by a biomimeti c reaction sequence. The two enantiomers were resolved by column chrom atography of one of the synthetic intermediates. On the basis of CD re sults a tentative absolute configuration for the synthetic enantiomers and natural 3',4-di-O-methylcedrusin is proposed.