COPPER(II) CHLORIDE-1-METHYLBENZOTRIAZOLE CHEMISTRY - VARIATION OF PRODUCT AS A FUNCTION OF METAL-TO-LIGAND REACTION RATIO - SYNTHESIS, STRUCTURE AND PROPERTIES OF A DINUCLEAR COMPLEX AND A NOVEL CHAIN POLYMERWITH 2 ALTERNATING CHROMOPHORES

Authors
SKORDA K BAKALBASSIS EG MROZINSKI J PERLEPES SP RAPTOPOULOU CP TERZIS A
Citation
K. Skorda et al., COPPER(II) CHLORIDE-1-METHYLBENZOTRIAZOLE CHEMISTRY - VARIATION OF PRODUCT AS A FUNCTION OF METAL-TO-LIGAND REACTION RATIO - SYNTHESIS, STRUCTURE AND PROPERTIES OF A DINUCLEAR COMPLEX AND A NOVEL CHAIN POLYMERWITH 2 ALTERNATING CHROMOPHORES, Journal of the Chemical Society. Dalton transactions, (13), 1995, pp. 2317-2319
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
13
Year of publication
1995
Pages
2317 - 2319
Database
ISI
SICI code
0300-9246(1995):13<2317:CCC-VO>2.0.ZU;2-P
Abstract
The 1:2 and 1:1 reactions of CuCl2 with 1-methylbenzotriazole in EtOH- CH(OEt)(3) gave the doubly chloro-bridged dimer [Cu2Cl4(C7H7N3)(4)] 1 and the novel alternating linear-chain polymer [{Cu2Cl4(C7H7N3)(2)}(n) ] 2 respectively, crystal structures of which have been determined; ma gnetic susceptibility studies show that complex 1 possesses intramolec ular- and complex 2 intrachain-ferromagnetic coupling.