REACTION OF CH2(PH(2)PSE)(2) WITH [RU-3(CO)(12)] - CRYSTAL-STRUCTURE OF [RU4SE4(CO)(10)(PH(2)PCH(2)PPH(2))], A MISSING LINK IN THE [M(4)E(4)L(12)] CUBANE SERIES (M=GROUP-8 METAL, E=CHALCOGENIDO LIGAND)

Authors
CAUZZI D GRAIFF C LANFRANCHI M PREDIERI G TIRIPICCHIO A
Citation
D. Cauzzi et al., REACTION OF CH2(PH(2)PSE)(2) WITH [RU-3(CO)(12)] - CRYSTAL-STRUCTURE OF [RU4SE4(CO)(10)(PH(2)PCH(2)PPH(2))], A MISSING LINK IN THE [M(4)E(4)L(12)] CUBANE SERIES (M=GROUP-8 METAL, E=CHALCOGENIDO LIGAND), Journal of the Chemical Society. Dalton transactions, (13), 1995, pp. 2321-2322
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
13
Year of publication
1995
Pages
2321 - 2322
Database
ISI
SICI code
0300-9246(1995):13<2321:ROCW[->2.0.ZU;2-L
Abstract
The bis(phosphine selenide) CH2(Ph(2)PSe)(2) and [RU(3)(CO)(12)] (1:1) reacted in toluene to give [Ru-3(mu(3)-Se)(2)(CO)(7)(dppm)], [Ru-4(mu (4)-Se)(2)(CO)(9)(dppm)] and [Ru-4(mu(3)-Se)(4)(CO)(10)(dppm)] (dppm = Ph(2)PCH(2)-PPh(2)), the last of which is the first reported 72-elect ron Ru-Se cubane-like cage complex.