INTRAMOLECULAR REACTIVITY - KETO PARTICIPATION IN THE HYDROLYSIS OF N-METHYL-N-(9-OXOBICYCLO[3.3.1]NONAN-2-ALPHA-YL) MORPHOLINIUM IODIDE, AND A CANNIZZARO-TYPE REACTION OF 3-(2-OXOCYCLOHEXYL)PROPANAL

Authors
CHANDRASEKHAR S VENKATESAN V
Citation
S. Chandrasekhar et V. Venkatesan, INTRAMOLECULAR REACTIVITY - KETO PARTICIPATION IN THE HYDROLYSIS OF N-METHYL-N-(9-OXOBICYCLO[3.3.1]NONAN-2-ALPHA-YL) MORPHOLINIUM IODIDE, AND A CANNIZZARO-TYPE REACTION OF 3-(2-OXOCYCLOHEXYL)PROPANAL, Journal of chemical research. Synopses, (5), 1995, pp. 170-171
Citations number
26
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
5
Year of publication
1995
Pages
170 - 171
Database
ISI
SICI code
0308-2342(1995):5<170:IR-KPI>2.0.ZU;2-Q
Abstract
Mechanistic studies of two intramolecular processes, nucleophilic disp lacement of N-methylmorpholinium in N-methyl-N-{9-oxobicyclo[3,3,1]non an-2 alpha-yl}morpholinium iodide, anchimerically assisted by keto car bonyl, and a Cannizzaro-type reaction of 3-(2-oxocyclohexyl)propanal, occurring via axial hydride transfer onto the cyclohexanone, are repor ted.