We have measured the thermopower S(T,H) and resistivity rho(T,H) of la
ser ablated La0.67Ca0.33MnO3 films, as a function of temperature and e
xternal magnetic field. On heating. a metal-insulator transition occur
s at temperatures below The resistivity peak, observed via a jump betw
een a low T regime, where S proportional to T, and a high T regime, wh
ere S proportional to 1/T. An applied magnetic field shifts the transi
tion in a postannealed sample to higher temperatures, causing a giant
magnetothermopower effect 100x(S-8T - S-0T)/S-8T = -1400%. Both S(T) a
nd rho(T) are activated at high temperatures, but with significantly d
ifferent activation energies. We interpret this as an evidence of smal
l polarons at high temperatures. (C) 1996 American Institute of Physic
s.