DIASTEREOSPECIFIC DIHYDROXYLATION AND HIGHLY EFFICIENT ASYMMETRIC DIHYDROXYLATION KINETIC RESOLUTION OF CIS TRANS-2,6-DIMETHYLBENZYLIDENECYCLOHEXANE/

Authors
GARDINER JM NORRET M SADLER IH
Citation
Jm. Gardiner et al., DIASTEREOSPECIFIC DIHYDROXYLATION AND HIGHLY EFFICIENT ASYMMETRIC DIHYDROXYLATION KINETIC RESOLUTION OF CIS TRANS-2,6-DIMETHYLBENZYLIDENECYCLOHEXANE/, Chemical communications, (24), 1996, pp. 2709-2710
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
24
Year of publication
1996
Pages
2709 - 2710
Database
ISI
SICI code
1359-7345(1996):24<2709:DDAHEA>2.0.ZU;2-S
Abstract
Achiral dihydroxylation and catalytic asymmetric dihydroxylation (AD) lead to reaction of only the cis (and not the trans) isomer of 2,6-dim ethylbenzylidenecyclohexane, dihydroxylation is diastereoisomer specif ic and an efficient kinetic resolution is achieved using AD.