SYNTHESIS AND MOLECULAR-STRUCTURE OF A TETRANUCLEAR VANADIUM(III)-MAGNESIUM(II) COMPLEX - A PROCATALYST FOR THE ALKENE POLYMERIZATION PROCESS

Authors
JANAS Z SOBOTA P KASPRZAK M GLOWIAK T
Citation
Z. Janas et al., SYNTHESIS AND MOLECULAR-STRUCTURE OF A TETRANUCLEAR VANADIUM(III)-MAGNESIUM(II) COMPLEX - A PROCATALYST FOR THE ALKENE POLYMERIZATION PROCESS, Chemical communications, (24), 1996, pp. 2727-2728
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
24
Year of publication
1996
Pages
2727 - 2728
Database
ISI
SICI code
1359-7345(1996):24<2727:SAMOAT>2.0.ZU;2-6
Abstract
Treatment of [VCl3(thf)(3)] (thf = tetrahydrofuran) with [Mg(thffo)(2) ] (thffo = 2-tetrahydrofurfuroxide) in 1:1.5 ratio in thf provides the tetranuclear 2(mu(3),eta(2)-thffo)(2)(mu,eta(2)-thffo)(4)Cl-4]. 2CH(2 )Cl(2) complex, for which a structural study and catalytic activity in ethene polymerization process are reported.