IMIDAZOQUINOLINETHIONES FROM QUINOLINES - A NEW MOLECULAR REARRANGEMENT

Citation
Cw. Rees et al., IMIDAZOQUINOLINETHIONES FROM QUINOLINES - A NEW MOLECULAR REARRANGEMENT, Chemical communications, (24), 1996, pp. 2775-2776
Citations number
6
Categorie Soggetti
Chemistry
Journal title
ISSN journal
13597345
Issue
24
Year of publication
1996
Pages
2775 - 2776
Database
ISI
SICI code
1359-7345(1996):24<2775:IFQ-AN>2.0.ZU;2-3
Abstract
8-Aminoquinolines and the dithiazolium salt 1 give N-(8-quinolinyl)imi nodithiazoles 4 which undergo an unusual type of thermal rearrangement to give the new imidazo[5,4,1-ij]quinoline-4-thiones 6; it appears th at the thione sulfur is delivered intramolecularly (9 --> 10).