HEXACYANOMETALATES AS TEMPLATES FOR HETEROPOLYNUCLEAR COMPLEXES AND MOLECULAR MAGNETS - SYNTHESIS AND CRYSTAL-STRUCTURE OF [FE((CN)CU(TPA))(6)][CLO4](8)CENTER-DOT-3H(2)O, [TPA EQUALS TRIS(2-PYRIDYLMETHYL)AMINE]

Authors
PARKER RJ HOCKLESS DCR MOUBARAKI B MURRAY KS SPICCIA L
Citation
Rj. Parker et al., HEXACYANOMETALATES AS TEMPLATES FOR HETEROPOLYNUCLEAR COMPLEXES AND MOLECULAR MAGNETS - SYNTHESIS AND CRYSTAL-STRUCTURE OF [FE((CN)CU(TPA))(6)][CLO4](8)CENTER-DOT-3H(2)O, [TPA EQUALS TRIS(2-PYRIDYLMETHYL)AMINE], Chemical communications, (24), 1996, pp. 2789-2790
Citations number
25
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
24
Year of publication
1996
Pages
2789 - 2790
Database
ISI
SICI code
1359-7345(1996):24<2789:HATFHC>2.0.ZU;2-O
Abstract
Reaction of [Fe(CN)(6)](3-) with [Cu(tpa)(OH2)](2+) produces a bimetal lic heptanuclear complex, [Fe{(CN)Cu(tpa)}(6)]-[ClO4](8) . 3H(2)O, whi ch is characterised by single-crystal X-ray diffraction and shown to c onsist of an iron(II) centre connected by cyano bridges to six copper( II) centres forming spherical units of [Fe{(CN)Cu(tpa)}(6)](8+).