CANA2P4O12, A NEW COMPOUND IN THE CA(PO3)(2)-NAPO3 SYSTEM

Citation
Mt. Averbuchpouchot, CANA2P4O12, A NEW COMPOUND IN THE CA(PO3)(2)-NAPO3 SYSTEM, European journal of solid state and inorganic chemistry, 33(1), 1996, pp. 15-18
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
09924361
Volume
33
Issue
1
Year of publication
1996
Pages
15 - 18
Database
ISI
SICI code
0992-4361(1996)33:1<15:CANCIT>2.0.ZU;2-P
Abstract
CaNa2P4O12 is a new cyclotetraphosphate which was not observed in the previous investigations of the Ca(PO3)(2)-NaPO3 system. This salt is t etragonal, P4/nbm, with Z = 2 and the following unit-cell dimensions: a=9.568(4), c=4.909(2) Angstrom. Its atomic arrangement refined with a final R value of 0.038 for a set of 266 independent reflections is si milar to that of the strontium derivative, SrNa2P4O12.