MIXED COORDINATION NUMBERS AND GEOMETRIES OF GOLD(I) IN A DINUCLEAR COMPLEX OF THIOGLYCEROL

Authors
LOPEZDELUZURIAGA JM SLADEK A SCHMIDBAUR H
Citation
Jm. Lopezdeluzuriaga et al., MIXED COORDINATION NUMBERS AND GEOMETRIES OF GOLD(I) IN A DINUCLEAR COMPLEX OF THIOGLYCEROL, Journal of the Chemical Society. Dalton transactions, (24), 1996, pp. 4511-4512
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
24
Year of publication
1996
Pages
4511 - 4512
Database
ISI
SICI code
0300-9246(1996):24<4511:MCNAGO>2.0.ZU;2-E
Abstract
Reaction of DL-3-sulfanylpropane-1,2-diol with [O(AuPPh(3))(3)]BF4 aff orded a dinuclear complex [Au-2(PPh(3))(3){SCH2CH(OH)CH2OH}] in which two gold environments, linear and trigonal planar, are present in the same molecule; the complex has been structurally characterized.