APPLICATION OF INDANE-DERIVED C-2-SYMMETRICAL BIS(OXAZOLINES) IN 2-POINT BINDING ASYMMETRIC DIELS-ALDER REACTIONS

Authors
DAVIES IW SENANAYAKE CH LARSEN RD VERHOEVEN TR REIDER PJ
Citation
Iw. Davies et al., APPLICATION OF INDANE-DERIVED C-2-SYMMETRICAL BIS(OXAZOLINES) IN 2-POINT BINDING ASYMMETRIC DIELS-ALDER REACTIONS, Tetrahedron letters, 37(11), 1996, pp. 1725-1726
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
11
Year of publication
1996
Pages
1725 - 1726
Database
ISI
SICI code
0040-4039(1996)37:11<1725:AOICBI>2.0.ZU;2-S
Abstract
Bis(oxazolines) 1 - 5 were examined in copper(II)-catalyzed asymmetric Diels-Alder reactions of acrylimide 6 and cyclopentadiene. Highly ena ntioselective reactions were attained with ligand 1 (up to 95% e.e.) a s well as good endo selectivity (39:1) in the Cu(SbF6)(2)-catalyzed pr ocess.