OXIDATION OF NATURAL COMPOUNDS CATALYZED BY MN(III) PORPHYRIN COMPLEXES

Authors
CAVALEIRO JAS NASCIMENTO GMSFC NEVES MGPMS PINTO MT SILVESTRE AJD VICENTE MGH
Citation
Jas. Cavaleiro et al., OXIDATION OF NATURAL COMPOUNDS CATALYZED BY MN(III) PORPHYRIN COMPLEXES, Tetrahedron letters, 37(11), 1996, pp. 1893-1896
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
11
Year of publication
1996
Pages
1893 - 1896
Database
ISI
SICI code
0040-4039(1996)37:11<1893:OONCCB>2.0.ZU;2-9
Abstract
The oxidation of 1,8-cineole (1) and methyl dehydroabietate (8b) by hy drogen peroxide, catalysed by Mn(III) porphyrin complexes, is reported . Five oxygenated products (2-6) have been obtained from reactions at positions 2 and 3 of 1,8-cineole and three oxygenated products (9-11) from the reaction at position 7 of methyl dehydroabietate.