THE SOLVENT PROMOTED ADDITION OF TETRAALLYLTIN TO ALDEHYDES - A CONVENIENT AND CHEMOSELECTIVE ALLYLATION PROCEDURE

Authors
COKLEY TM MARSHALL RL MCCLUSKEY A YOUNG DJ
Citation
Tm. Cokley et al., THE SOLVENT PROMOTED ADDITION OF TETRAALLYLTIN TO ALDEHYDES - A CONVENIENT AND CHEMOSELECTIVE ALLYLATION PROCEDURE, Tetrahedron letters, 37(11), 1996, pp. 1905-1908
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
11
Year of publication
1996
Pages
1905 - 1908
Database
ISI
SICI code
0040-4039(1996)37:11<1905:TSPAOT>2.0.ZU;2-S
Abstract
Aldehydes 2a - e react with tetraallyltin (1,0.25 equiv.) in methanol or other polar solvent at room temperature (ca 30 degrees C, <20 h) to provide the corresponding homoallyl alcohols 3a - e in 69 - 98% yield . No additional catalysis is required.